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Can only access homepage and admin panel

I am really struggling to move WordPress from an external host to my localhost (xampp). After two days trying to do this I am now at the stage where I can access the homepage and admin panel, but nothing else.

I have accessed permalinks and clicked save as shown below:

Here is the .htaccess file that is generated:

# BEGIN WordPress
<IfModule mod_rewrite.c>
RewriteEngine On
RewriteBase /Blog/
RewriteRule ^index.php$ - [L]
RewriteCond %{REQUEST_FILENAME} !-f
RewriteCond %{REQUEST_FILENAME} !-d
RewriteRule . /Blog/index.php [L]
</IfModule>

# END WordPress

Here is the apache config:

Options All

AllowOverride All

and:

LoadModule rewrite_module modules/mod_rewrite.so

For example, when I try to access: http://ianscomputer/Blog/about-2/; I see this in Fiddler:

What is the problem?

Update
Here are some more settings: